The optimal allocation of sediment resources needs to balance three objectives including ecological, economic, and social benefits so as to realize sustainable development of sediment resources. This study aims to apply fuzzy programming and bargaining approaches to solve the problem of optimal allocation of sediment resources. Firstly, Pareto-optimal solutions of multi-objective optimization were introduced, and the multi-objective optimal allocation model of sediment resources and fuzzy programming model was constructed. Then, from the perspective of multiplayer cooperation, the optimal allocation model of sediment resources was transformed into a game model by using Nash bargaining, and Nash bargaining solution was obtained as the optimal equilibrium strategy. Finally, the influence of different disagreement utility points and bargaining weights on the results was discussed, and the results of Nash bargaining and fuzzy programming methods were compared and analyzed. Results corroborate that Nash bargaining can achieve the cooperative optimization of multiple objectives with competitive relationship and obtain satisfactory scheme. Disagreement utility points and bargaining weights have a certain impact on the optimization results. The solution of fuzzy programming is close to that of Nash bargaining, which provides different ideas for multi-objective optimization problem.
Organochlorine pesticides (OCPs) have variously been phased out in agricultural activities, but they are still widely detected in air, water, and soil systems due to their recalcitrant nature in the environment. The purposes of this study were to assess potential OCP pollution via dry and wet deposition over the fast developing Pearl River Delta area with 41,700 km2, where the main effort has been focused on emerging pollutants such as petroleum hydrocarbons and PM2.5. We quantified both the dry and wet deposition fluxes of 19 OCPs including dichlorodiphenyltrichloroethanes (DDTs), endosulfans (Endos), and hexachlorocyclohexanes (HCHs). The results showed that each year about 67.4, 42.0, 15.0, and 8.07 kg of total OCPs, DDTs, Endos, and HCHs were returned to the ground, among which 11.7, 10.4, 0.84, and 0.16 kg were in the dry deposition forms. The large spatial variations in OCP deposition fluxes indicated that OCP pollution in the air is mainly influenced on local scales because evaporation from local soil is likely the major source of the phased out OCPs. Source analysis indicated that DDTs may be still in use as antifouling agent and/or dicofol, but Endos and HCHs were mainly derived from the residual of historical usage. The study suggests that the historical OCP pollutants are persistent at high levels in this area and should not be overlooked, while we tackle emerging pollutants. 相似文献
Concentrations of Cu, Pb, and As were determined in seawater, surface sediment, Sargassum pallidum collected from the Daya Bay, China. The influence of metal contamination on the marine alga was investigated at chemical and ultrastructural level. Mean concentrations of Cu (19.44 mg kg?1) and Pb (33.99 mg kg?1) were found to be high in sediment, whereas concentration of As (122.29 mg kg?1) in S. pallidum was higher than that in water and sediment. The ultrastructure of S. pallidum cells was anomalous and aberrant. Energy-dispersive x-ray spectroscopic analysis revealed that the nanometal particles in the form of comparatively high-electron density substance diffused in the cell structures constituted by Cu, Pb, As, etc. There is a remarkable similarity or correspondence in the anomalous elements between the geochemistry and the botanic cell, and the heavy metals have potential hazardous effect on the ocean ecology system in Daya Bay. 相似文献